METAL ORGANIC FRAMEWORKS (TOXIC GAS REMOVAL)

 

Introduction

FERROLOX-XG is Carbon based Metal-Organic-Frameworks for removal of toxic gases. Removing the troublesome and highly toxic impurities of Hydrogen Sulfide (H2S) and Carbon-dioxide from gases has become so simple and highly effective using a Metal (Iron Hydroxide) Organic (Carbon) Framework (MOF) developed by Watch Water Germany.

Upgrading gases with FERROLOX-XG could help the entire world to make greater and cleaner use of gases including natural gas supplies, which can contain high level of toxic impurities. FERROLOX-XG can be used to clean natural gases and other industrial gases containing H2S and CO2 worldwide to reap potentially large environmental and economic benefits.

 

 

Applications

Oil & Gas Industry

Refineries

Gases in Oil Well

Fuel Tanks

Biogas

Waste Water and Odour

 

 

Best Features

 

  • Capturing and degradation of toxic gases and vapours
  • Removal of highly toxic impurities of Hydrogen Sulfide
  • Simple and highly effective
  • Helps to make gases cleaner
  • Removal of troublesome impurities from gases
  • Removal of highly toxic impurities of Carbon dioxide

 

 

 

 

Operating Parameters

 

Operating Parameters:
Inlet H2S concentration 50 mg/l to 15000 mg/l
Bed height Min: 0.5 m
Max: 12 m
Pressure loss in filter bed < 1 to 15 mbar depending upon bed height and granule size
Pressure range No pressure – ca. 25 bar overpressure
Backwash Velocity US 10 – 12 gpm/ft2
Relative gas moisture Min: 40 %
Optimal: 60 % – 80 %

 

FREQUENTLY ASKED
QUESTIONS

FERROLOX-XG® is a Carbon-based Metal-Organic-Framework (MOF) adsorber designed by Watch Water GmbH, Germany for the removal of toxic and corrosive gases such as Hydrogen Sulfide (H₂S) and Carbon Dioxide (CO₂) from gas streams. It combines iron hydroxide [Fe(OH)₃] and carbon within a porous MOF lattice, giving it extraordinary selectivity, surface area, and regenerability.

Traditional gas purification materials (e.g., iron sponge, activated carbon) are non-regenerable, produce hazardous waste, and have low sulfur retention. FERROLOX-XG® overcomes these limitations by offering:

  • Hybrid MOF design – carbon core + iron shell for dual adsorption & catalytic oxidation
  • Extremely high surface area (~ 1,800–2,000 m²/g)
  • Self-renewing capability via OXYDES-XG (solid-oxygen regeneration)
  • Multi-gas adsorption (H₂S, CO₂, CO, SOₓ, NOₓ, NH₃, VOCs)
  • No liquid bubbling or waste effluent

The MOF structure is a Lignin-based Organic Polymer (LOP) with extremely high porosity. Iron(III) ions are anchored on the carbon framework, forming an active ferric-oxide network that reacts with both organic and inorganic gas molecules. This gives FERROLOX-XG® its unique ability to adsorb, oxidize, and be regenerated repeatedly.

  • Natural-gas and biogas upgrading
  • Refineries and petrochemical plants
  • Oil & gas production and storage facilities
  • Landfills and waste-gas treatment systems
  • Industrial air scrubbers and odor control units
  • Environmental cleanup of toxic and VOC-laden air
Parameter Recommended Range
Inlet H₂S Concentration 50 – 15 000 mg/L
Bed Height 0.5 – 12 m
Pressure Loss < 1 – 15 mbar (depending on bed height & granule size)
Pressure Range 0 – 25 bar
Contact Time 20 sec – 3 min
Relative Gas Moisture ≥ 40 % (optimum 60–80 %)
Operating Temperature Ambient to ~60 °C (avoid sulfur ignition > 190 °C)

Conventional air bubbling does not effectively regenerate MOFs due to bio-film formation. OXYDES-XG® is a proprietary solid-oxygen granular material that delivers oxygen by diffusion directly onto the adsorber surface — no bubbling needed. It:

  • Restores adsorption capacity within minutes
  • Oxidizes toxic gases and organics into CO₂ and H₂O
  • Prevents biofouling and surface clogging
  • Eliminates disposal of non-regenerable adsorbers

Result: a continuous, self-sustaining, “green-chemistry” regeneration process.

  • Maintain minimum 40 % humidity for optimal reaction.
  • Avoid sudden oxygen injection in partially regenerated beds – sulfur may ignite at $190–260 °C.
  • Ensure steady gas flow and proper ventilation.
  • Avoid direct contact with liquid water to prevent media degradation.
Property Value
Base Material Carbon + Iron (III) Hydroxide MOF
Form Granular solid
Color Dark brown / black
BET Surface Area $\sim 1 880 – 2 000 m²/g
Regeneration Agent OXYDES-XG (solid oxygen)
Relative Moisture 40 – 80 %
Operating Pressure Up to 25 bar
Typical Lifetime Multiple regeneration cycles

With OXYDES-XG regeneration, the system can break down or oxidize:

  • Sulfur compounds → elemental S
  • Ammonia / amines → N₂ + H₂O
  • VOCs / hydrocarbons → CO₂ + H₂O
  • CO / NOₓ / SOₓ → harmless oxides or salts

This makes FERROLOX-XG a dual-function media — adsorber and catalytic oxidizer.

Yes. While specifically engineered for gas purification, the same MOF principle is applicable for removing toxic metals and organics from water and wastewater. FERROLOX-X is the corresponding media for water systems; FERROLOX-XG is optimized for gas.

  • ✅ Regenerable – no hazardous solid waste
  • ✅ Operates without liquid brine or chemical regenerants
  • ✅ Captures CO₂ and H₂S simultaneously → lowers GHG impact
  • ✅ Promotes reuse and long service life
  • ✅ Complies with Watch Water’s green-chemistry principles

Yes – it is a solid, non-toxic material when handled properly. Observe the same precautions as with other iron-based media: avoid dust inhalation and ensure ventilation in H₂S areas. Always follow site-specific safety procedures.

FERROLOX-XG® is manufactured by Watch Water GmbH, Fahrlachstraße 14, 68165 Mannheim, Germany — an industry leader in advanced MOF-based adsorbers and regenerative technologies such as OXYDES-XG and SolarOxy-3C.

  • ✅ Removes both acidic and toxic gases (H₂S, CO₂, SOₓ, NOₓ, NH₃, VOCs)
  • ✅ Reusable and regenerable with OXYDES-XG
  • ✅ High surface area and adsorption rate
  • ✅ Low pressure drop, wide operating range (0–25 bar)
  • ✅ Environmentally friendly — no liquid waste
  • ✅ Compact design for retrofit into existing gas systems
  • ✅ Made in Germany under Watch Water quality standards